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請(qǐng)問(wèn)各位大佬們,我最近投稿,審稿人提出一個(gè)關(guān)于過(guò)渡態(tài)和速率問(wèn)題,見(jiàn)下文(包括問(wèn)題涉及的相關(guān)內(nèi)容)。這個(gè)我不太懂,能否請(qǐng)大佬們幫我看看,如何回答。非常感謝各位大佬們[抱拳][抱拳][玫瑰][玫瑰] The discussion of the uranium chemistry has issues with it. There will be no transition state unless the reaction intermediate is quenched and with that much energy being released, that is unlikely. Effectively there is no barrier, and the reaction should be diffusion controlled. What is the diffusion controlled rate constant going to be? Scheme 1. hypothesized pathway of CO2 cleavage promoted by complexes RM (M = Cr, Mo, W and U). Fig. 3. Gibbs free energy (ΔrG) profile for the pathway of the U complex-triggered reaction. @jiagle @我想更懂你29 發(fā)自小木蟲(chóng)Android客戶(hù)端 |
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