| 1 | 1/1 | 返回列表 |
| 查看: 413 | 回復: 0 | ||
| 【懸賞金幣】回答本帖問題,作者18249356421將贈送您 35 個金幣 | ||
18249356421新蟲 (初入文壇)
|
[求助]
擴散控制速率
|
|
|
請問各位大佬們,我最近投稿,審稿人提出一個關于過渡態(tài)和速率問題,見下文(包括問題涉及的相關內(nèi)容)。這個我不太懂,能否請大佬們幫我看看,如何回答。非常感謝各位大佬們[抱拳][抱拳][玫瑰][玫瑰] The discussion of the uranium chemistry has issues with it. There will be no transition state unless the reaction intermediate is quenched and with that much energy being released, that is unlikely. Effectively there is no barrier, and the reaction should be diffusion controlled. What is the diffusion controlled rate constant going to be? Scheme 1. hypothesized pathway of CO2 cleavage promoted by complexes RM (M = Cr, Mo, W and U). Fig. 3. Gibbs free energy (ΔrG) profile for the pathway of the U complex-triggered reaction. @jiagle @我想更懂你29 發(fā)自小木蟲Android客戶端 |
| 1 | 1/1 | 返回列表 |
| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 歡迎采礦、地質(zhì)、巖土、計算機、人工智能等專業(yè)的同學報考 +10 | pin8023 2026-02-28 | 13/650 |
|
|---|---|---|---|---|
|
[考研] 一志愿南京大學資源與環(huán)境專業(yè)283分求調(diào)劑 +3 | 追云?? 2026-03-04 | 3/150 |
|
|
[考研] 0817化學工程與技術312分求調(diào)劑 +3 | T123 tt 2026-03-04 | 3/150 |
|
|
[考研] 0856材料與化工,270求調(diào)劑 +17 | YXCT 2026-03-01 | 20/1000 |
|
|
[考研] 085600材料與化工 298 調(diào)劑 +9 | 小西笑嘻嘻 2026-03-03 | 9/450 |
|
|
[基金申請] 沒有青基直接申請面上,感覺自己瘋了 +6 | kevin63t 2026-03-02 | 12/600 |
|
|
[考研] 化學工程求調(diào)劑 +10 | 化工人999 2026-03-04 | 10/500 |
|
|
[考研] 289求調(diào)劑 +8 | yang婷 2026-03-02 | 10/500 |
|
|
[考研] 0854總分272 +5 | 打小就是老實人 2026-03-02 | 6/300 |
|
|
[考研] 復試調(diào)劑 +4 | 杰尼龜aaa 2026-03-03 | 4/200 |
|
|
[考研] 293求調(diào)劑 +4 | 是樂渝哇 2026-03-03 | 4/200 |
|
|
[考研] 298求調(diào)劑 +3 | 人間唯你是清歡 2026-03-03 | 4/200 |
|
|
[考研] 0857調(diào)劑 +6 | 一ll半 2026-02-28 | 8/400 |
|
|
[考研] 清華大學 材料與化工 353分求調(diào)劑 +5 | awaystay 2026-03-02 | 6/300 |
|
|
[考研] 求調(diào)劑 +11 | yunziaaaaa 2026-03-01 | 13/650 |
|
|
[考研] 295求調(diào)劑。一志愿報考鄭州大學化學工藝學碩,總分295分 +8 | yl1 2026-03-02 | 9/450 |
|
|
[考研] 材料與化工328求調(diào)劑 +3 | 。,。,。,。i 2026-03-02 | 3/150 |
|
|
[考研] 化工專碩342,一志愿大連理工大學,求調(diào)劑 +6 | kyf化工 2026-02-28 | 7/350 |
|
|
[考研] 299求調(diào)劑 +3 | Y墨明棋妙Y 2026-02-28 | 5/250 |
|
|
[考研] 0856材料求調(diào)劑 +4 | 麻辣魷魚 2026-02-28 | 4/200 |
|