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卡片號為ICSD 240929 物質(zhì)名稱Mn[Fe(CN)6]0.6667·nH2O;卡片號為JCPDS 89-8979 已有1人參與
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求助CIF文件 卡片號為ICSD 240929 物質(zhì)名稱Mn[Fe(CN)6]0.6667·nH2O;卡片號為JCPDS 89-8979 |
新蟲 (著名寫手)
新蟲 (著名寫手)
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*data for ICSD #240929 CopyRight ?2010 by Fachinformationszentrum Karlsruhe, and the U.S. Secretary of Commerce on behalf of the United States. All rights reserved. Coll Code 240929 Rec Date 2008/08/01 Chem Name Poly[[hexa-mue-cyanido-manganese(II)iron(III)] Pentahydrate] Structured Mn [Fe (C N)6]0.6667 (H2 O)5 Sum C4.0002 H10 Fe0.6667 Mn1 N4.0002 O5 ANX A3B4C16X16Y20 D(calc) 1.7 Title Poly[[hexa-mu-cyanido-manganese(II)iron(III)] pentahydrate] Author(s) Matsuda, T.;Tokoro, H.;Shiro, M.;Hashimoto, K.;Ohkoshi, S. Reference Acta Crystallographica E , Structure Reports Online (2008), 64(2), i11-i12 Unit Cell 10.3859(13) 10.3859(13) 10.3859(13) 90.0000 90.0000 90.0000 Vol 1120.29 Z 4 Space Group F m -3 m SG Number 225 Cryst Sys cubic Pearson cF99 Wyckoff k f e2 c b a R Value .0469 Red Cell F 7.343 7.343 7.343 60 60 60 280.074 Trans Red 0.500 0.500 0.000 / 0.000 0.500 0.500 / 0.500 0.000 0.500 Comments Experimental density determined by flotation in toluene and tetrabromomethane Temperature in Kelvin: 90 Temperature factors available X-ray diffraction from single crystal Unusual difference between calculated and measured density Atom # OX SITE x y z SOF H ITF(U) Fe 1 +3 4 a 0.5000 0.5000 0.0000 0.6667 0 0.0176(2) Mn 1 +2 4 b 0.5000 0.5000 0.5000 1.00 0 0.0183(2) O 1 -2 96 k 0.4576(10) 0.4576(10) 0.2922(11) 0.0833 0 0.036(3) O 2 -2 8 c 0.7500 0.2500 0.2500 0.8333 0 0.096(6) O 3 -2 32 f 0.6550(16) 0.3450(16) 0.1550(16) 0.1667 0 0.054(6) N 1 -3 24 e 0.5000 0.5000 0.2973(12) 0.6667 0 0.086(3) C 1 +2 24 e 0.5000 0.5000 0.1847(8) 0.6667 0 0.064(2) Lbl Type U11 U22 U33 U12 U13 U23 Fe1 Fe3+ 0.0176(2) 0.0176(2) 0.0176(2) 0.0000 0.0000 0.0000 Mn1 Mn2+ 0.0183(2) 0.0183(2) 0.0183(2) 0.0000 0.0000 0.0000 O1 O2- 0.052(5) 0.052(5) 0.006(3) -0.026(5) -0.002(2) -0.002(2) O2 O2- 0.096(6) 0.096(6) 0.096(6) 0.0000 0.0000 0.0000 O3 O2- 0.054(6) 0.054(6) 0.054(6) -0.018(6) 0.018(6) -0.018(6) N1 N3- 0.114(5) 0.114(5) 0.030(3) 0.0000 0.0000 0.0000 C1 C2+ 0.085(4) 0.085(4) 0.023(2) 0.0000 0.0000 0.0000 Std. Notes Transformation Method: Tidy Std. Cell 10.3859 10.3859 10.3859 90 90 90 Std. Vol. 1120.3 Std. Z 4 Std. SG FM3-M Std. Atom Atom # OX SITE x y z SOF Fe 1 +3 4 a 0 0 0 0.666700 Mn 1 +2 4 b .5 .5 .5 1. O 1 -2 96 k .04240 .04240 .29220 0.083300 O 2 -2 8 c .25 .25 .25 0.833300 O 3 -2 32 f .15500 .15500 .15500 0.166700 N 1 -3 24 e .29730 0 0 0.666700 C 1 +2 24 e .18470 0 0 0.666700 *end for ICSD #240929 |
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