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investigation of gd, ca and nd tri-doped ceria for application in solid oxide fuel cells doi10.2298/pac2402123w processing and application of ceramics volume18issue2page123-129 |
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Investigation of Gd, Ca and Nd tri-doped ceria for application in solid oxide fuel cells By Wang, M (Wang, Ming) [1] ; Hou, YF (Hou, Yifeng) [1] ; Cheng, JH (Cheng, Jihai) [1] (provided by Clarivate) Source PROCESSING AND APPLICATION OF CERAMICS Volume18Issue2Page123-129 DOI10.2298/PAC2402123W Published 2024 Indexed 2024-07-18 Document Type Article Abstract Nanosized tri-doped ceria powders with composition Ce 0.8 Gd 0.15 Ca 0.05-x Nd x O 2-6 (CGCN, x = 0.0125, 0.025, 0.0375) were obtained by sol-gel methods. The powders were compressed into discs and sintered in air to form perspective solid electrolytes. The obtained samples were characterized by X-ray di f f raction (XRD), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS) methods. XRD and SEM analyses confirm that the samples are densified and have fluorite structure after sintering at 1350 degrees C. Among all Ce 0.8 Gd 0.15 Ca 0.05-x Nd x O 2-6 samples, the sintered Ce 0.8 Gd 0.15 Ca 0.025 Nd 0.025 O 2-6 electrolyte has the highest conductivity of 2.5 x 10 -2 S / cm at 800 degrees C and the corresponding activation energy is 0.64 eV. Keywords Author Keywordssolid oxide fuel cellselectrolytedoped-CeO 2structureelectrical conductivity Keywords PlusELECTRICAL-PROPERTIESELECTROLYTECONDUCTIVITYCEO2CATHODESTRAIN Author Information Corresponding Address Cheng, Jihai (corresponding author) Hefei Univ, Sch Energy Mat & Chem Engn, Hefei 230022, Peoples R China E-mail Addresses cjh@hfuu.edu.cn Addresses 1 Hefei Univ, Sch Energy Mat & Chem Engn, Hefei 230022, Peoples R China E-mail Addresses cjh@hfuu.edu.cn Categories/ Classification Research AreasMaterials Science Web of Science Categories Materials Science, Ceramics Funding Funding agency Grant number Natural Science Foundation of Anhui Province Language English Accession Number WOS:001266783100001 ISSN 1820-6131 eISSN 2406-1034 IDS Number YE3Z3 |
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3樓2024-11-22 11:46:21
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