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做做實(shí)驗(yàn)新蟲 (初入文壇)
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[求助]
回稿,計(jì)算結(jié)合常數(shù)(非B-H方程)
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今日求助,回稿里有一個(gè)問(wèn)題是讓我用非benesi-Hildebrand方程求結(jié)合常數(shù),原文如下: Authors applied linear regression Benesi-Hildebrand method to determine association constant Kass. However, this method is not valid for high Ka values (this method correctly describes only soft complex binding; up to K = 5000 mol-1 dm3). Therefore, they should use rather a non-linear regression approach for more precise association constant determination (Chem. Soc. Rev. 2011, 40, 1305-1323). This approach is not difficult with modern computer technology and there is no real excuse for using old-fashion linear transformations anymore (as perfectly summarized by Pall Thordarson in Chem. Soc. Rev. 2011, 40, 1305-1323). 文獻(xiàn)我也看了,但是完全看不懂的,不知道吧里有高手會(huì)算這個(gè)嘛?(文獻(xiàn)同時(shí)附上) |
銅蟲 (初入文壇)
新蟲 (小有名氣)
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